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51.
For B2 NiAl and NiTi intermetallic compounds, the ideal stress–strain image is lack from the perspective of elastic constants. We use first-principles calculation to investigate the ideal strength and elastic behavior under the tensile and shear loads. The relation between the ideal strength and elastic constants is found. The uniaxial tension of NiAl and NiTi along <001> crystal direction leads to the change from tetragonal path to orthogonal path, which is driven by the vanishing of the shear constant C(66). The shear failure under {110}{111} shear deformation occurring in process of tension may result in a small ideal tensile strength(~ 2 GPa) for NiTi. The unlikeness in the ideal strength of Ni Al and Ni Ti alloys is discussed based on the charge density difference. 相似文献
52.
天然气水合物作为一种储量大、无污染的清洁能源近些年受到了广泛关注. 近20年来,中国进行了较大范围的陆海域天然气水合物储层勘探与储量预测.2017年,中国地质调查局牵头对南海神狐海域的天然气水合物进行了基于降压渗流原理的试验性开采.国内外已进行的水合物试采工程面临着气体产量低、出砂较多等问题,其最主要的原因之一是开发过程中沉积物内复杂多相渗流机理尚不明晰.本文综述了平行毛细管模型、Kozeny模型等广泛应用于天然气水合物开发渗流分析的理论模型,对比分析了水合物开发多尺度渗流过程模拟方法,简述了国内外含水合物沉积物渗透率测试、渗流过程中沉积物物性演变以及水合物开采室内模拟等方面的渗流实验进展,总结了矿场尺度的天然气水合物储层开采过程中产气数值模拟手段,展望了多相渗流模型、储层原位含水合物样品室内测试及结构与物性演化、矿场尺度数值模拟与水平井压裂技术等应用研究的未来方向与挑战. 相似文献
53.
Yu Chen Cagri Ayranci Tian Tang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(9):1539-1549
Viscoelastic properties of moisture-sensitive polymers can be significantly affected by moisture in the ambient environment, resulting in drastic changes in the properties as the absorbed moisture content increases. In this article, a simple yet important modification to the Reimschuessel model is introduced by considering both plasticization and anti-plasticization induced by water molecules. The proposed model is validated against the results of four different polymers obtained by Onogi et al., which demonstrates its capability of describing the available data. This model can be used to estimate the performance and service life of products produced using moisture-sensitive polymers. It also reveals that small amounts of diffused moisture might have a stiffening effect on the mechanical properties of hydrophilic polymers. 相似文献
54.
Dr. Shang-Bo Yu Dr. Furong Lin Prof. Jia Tian Dr. Yi Liu Prof. Dan-Wei Zhang Prof. Zhan-Ting Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(36):e202200914
Selective preparation of two-dimensional polymers (2DPs) and supramolecular polymers (2DSPs) with defined thickness is crucially important for controlling and maximizing their functions, yet it has remained as a synthetic challenge. In the past decade, several approaches have been developed to allow selective preparation of discrete monolayer 2DPs and 2DSPs. Recently, crystal exfoliation and self-assembly strategies have been employed to successfully prepare bilayer 2DP and 2DSP, which represent the first step towards the controlled “growth” of 2D polymers from the thinnest monolayers to thicker few-layers along the third dimension. This Concept review discusses the concept of accurate synthesis of 2D polymers with defined layers. Advances in this research area will pave the way to rational synthetic strategies for 2D polymers with controlled thickness. 相似文献
55.
The Ramanujan Journal - Elliptic integrals are of cardinal importance in mathematical analysis and in the field of applied mathematics. Since they cannot be represented by the elementary... 相似文献
56.
Xingxing Ge Xicheng Liu Zhenzhen Tian Shujiao Chen Xinyu Liu Lihua Guo Peiwei Gong Baoping Ling Xiang‐Ai Yuan Zhe Liu 《应用有机金属化学》2019,33(11)
Four half‐sandwich rutheniumII (RuII) complexes with triphenylamine‐modifed dipyridine frameworks were synthesized and characterized. The cytotoxicity of target complexes toward A549 (lung cancer cells), HeLa (cervical cancer cells) and HepG2 (hepatoma cells) were obtained by the MTT assay, which were superior to cisplatin with the IC50 values changed from 2.4 ± 0.1 μM to 9.2 ± 2.7 μM. Meanwhile, complexes possess the ability of antimetastasis to cancer cells. RuII complexes could be transported by serum albumin, catalyze the conversion of NADH (the reduced state of nicotinamide‐adenine dinucleotide) to NAD+ and induce the accumulation of reactive oxygen species, which confirmed the antineoplastic mechanism of oxidation. RuII complexes could enter A549 cells followed by a non‐energy dependent cellular uptake mechanism, target lysosomes with the Pearson's colocalization coefficient of 0.75, lead to lysosomal damage, disturb the cell cycle (S phase), and eventually induce apoptosis. The results demonstrate that these RuII complexes are potential anticancer agents with dual functions, including metastasis inhibition and lysosomal damage. 相似文献
57.
58.
This paper deals with the chemotaxis-growth system: , , in a smooth bounded domain with zero-flux boundary conditions, where μ, δ, and τ are given positive parameters. It is shown that the solution exponentially stabilizes to the constant stationary solution in the norm of as provided that and any given nonnegative and suitably smooth initial data fulfills , which extends the condition in [8]. 相似文献
59.
Deliang Kong Lihua Guo Meng Tian Shumiao Zhang Zhenzhen Tian Huayun Yang Ye Tian Zhe Liu 《应用有机金属化学》2019,33(1)
Fifteen organometallic Ir(III) half‐sandwich complexes ( 1A – 5C ) having the general formula [(η5‐Cpx)Ir(N^N)Cl]PF6 (Cpx = Cp*, tetramethyl(phenyl)cyclopentadienyl (Cpxph) or tetramethyl(biphenyl)cyclopentadienyl (Cpxbiph); N^N = diamine) have been synthesized and characterized. The molecular structure of 1A was determined using single‐crystal X‐ray diffraction analysis. The hydrolysis of 1A – 5C was monitored using UV–visible spectra. Complexes 3A – 3C showed catalytic activity for the oxidation of NADH to NAD+, where 3C showed the highest turnover number of 29.9 within 450 min. Cytotoxicity examination by MTT assay was carried out against two human cancer cell lines (HeLa and A549) after 24 or 48 h drug treatment. The complexes showed high potency, where the most potent complex ( 3C ; IC50 = 3.4 μM) was six times more active than cisplatin against A549 cells after 24 h drug exposure. Cytotoxic potency towards A549 cells increased with phenyl substitution on Cp ring: Cpxbiph > Cpxph > Cp*. In addition, the biological studies showed that 3C caused cell apoptosis and cell cycle arrest at G1 phase in A549 cancer cells. Moreover, 3C increased the level of reactive oxygen species markedly after 24 h, which may provide an important basis for killing cancer cells. Confocal laser scanning microscopy was used to track 3C in A549 cells. The cellular localization experiment showed that 3C targeted lysosomes and caused lysosomal damage. 相似文献
60.
Shuo Huang Jiacai Zhu Prof. Jinlei Tian Prof. Zhiqiang Niu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(64):14480-14494
Rechargeable aqueous zinc-ion batteries (ZIBs) have garnered tremendous attention in the field of next energy storage devices due to their high safety, low cost, abundant resources, and eco-friendliness. As an important component of the zinc-ion battery, the electrolyte plays a vital role in the electrochemical properties, since it will provide a pathway for the migrations of the zinc ions between the cathode and anode, and determine the ionic conductivity, electrochemically stable potential window, and reaction mechanism. In this Minireview, a brief introduction of electrochemical principles of the aqueous ZIBs is discussed and the recent advances of various aqueous electrolytes for ZIBs, including liquid, gel, and multifunctional hydrogel electrolytes are also summarized. Furthermore, the remaining challenges and future directions of electrolytes in aqueous ZIBs are also discussed, which could provide clues for the following development. 相似文献